課程名稱Course Title (中文) 化工熱力學 (英文) Chemical Engineering Thermodynamics 開課單位Departments 化學工程與生物科技學系 課程代碼Course No. C2100 授課教師Instructor 陳嘉明 學分數Credit 3.0 必/選修core required/optional 選修 開課年級Level 大三 先修科目或先備能力(Course Pre-requisites)：質能平衡　物理化學 課程概述與目標(Course Overview and Goals)：The course goal is to promote students to understand the basic principles and applications of chemical engineering thermodynamics. Classic thermodynamics will be reviewed first, followed by some specific topics including equation of state data analysis, chemical reaction equilibrium calculation, phase equilibrium data analysis, adsorption data analysis, etc. 教科書(Textbook) Stanley I. Sandler, " Chemical, Biochemical, and Engineering Thermodynamics " 5th ed., John Wiley & Sons, 2018 參考教材(Reference) J. M. Smith, "Introduction to Chemical Engineering Thermodynamics" 7th ed., McGraw-Hill, 2005
 課程大綱 Syllabus 學生學習目標Learning Objectives 單元學習活動Learning Activities 學習成效評量Evaluation 備註Notes 序No. 單元主題Unit topic 內容綱要Content summary 1 INTRODUCTION Introduction to Thermodynamics Data Regression SI Unit and Unit Conversion Commonly-used Thermodynamic Terms Equation of State Introduction to Thermodynamics Data Regression SI Unit and Unit Conversion Commonly-used Thermodynamic Terms Equation of State 2 CONSERVATION OF MASS General Balance Equation Application of Mass Balance to a Water Tank Conservation of Mass General Balance Equation Application of Mass Balance to a Water Tank Conservation of Mass 3 CONSERVATION OF ENERGY The first law of thermodynamics in closed system System total energy Work for reversible processes Work for irreversible processes The first law of thermodynamics in closed system System total energy Work for reversible processes Work for irreversible processes 4 CONSERVATION OF ENERGY Internal energy Internal energy as s state function of Temperature and volume Internal energy Internal energy as s state function of Temperature and volume 作業 HW 1 6% 5 ENTROPY: AN ADDITIONAL BALANCE EQUATION Concept of entropy in closed system State functions derived from entropy Heat, work, engines, and entropy 6 ENTROPY: AN ADDITIONAL BALANCE EQUATION The Entropy Balance Reversibility Heat, work, engines, and entropy The Entropy Balance Reversibility Heat, work, engines, and entropy 作業 HW 2 6% 7 Spring break holiday Self study of Aspen Learn how to use Aspen 8 MIDTERM EXAM Midterm Midterm 期中考 Midterm 30% 9 LIQUEFACTION, POWER CYCLES, AND EXPLOSIONS Liquefaction Power generation and refrigeration Liquefaction Power generation and refrigeration 作業 HW 3 6% 10 THE THERMODYNAMIC PROPERTIES OF REAL SUBSTANCES U = U(T, V) H = H(T, P) S = S(T, V), S = S(T, P) G = G(T, P) A = A(T, V) Reference state U = U(T, V) H = H(T, P) S = S(T, V), S = S(T, P) G = G(T, P) A = A(T, V) Reference state 11 THE THERMODYNAMIC PROPERTIES OF REAL SUBSTANCES Evaluation of state function change from equation of state Examples and applications Evaluation of state function change from equation of state Examples and applications 作業 HW 4 6% 12 THE THERMODYNAMICS OF MULTICOMPONENT MIXTURES Partial molar Gibbs free energy Heat of reaction in multicomponent mixtures Determination of partial molar volume and enthalpy Partial molar Gibbs free energy Heat of reaction in multicomponent mixtures Determination of partial molar volume and enthalpy 作業 HW 5 6% 13 ESTIMATION OF THE GIBBS ENERGY AND FUGACITY OF A COMPONENT IN A MIXTURE Ideal gas mixture Partial molar Gibbs energy and fugacity Fugacity of species in gaseous, liquid, and solid mixture Activity coefficient models Ideal gas mixture Partial molar Gibbs energy and fugacity Fugacity of species in gaseous, liquid, and solid mixture Activity coefficient models 14 VAPOR-LIQUID EQUILIBRIUM IN MIXTURES Introduction to Vapor-Liquid Equilibrium VLE in ideal mixtures VLE in non-ideal mixtures Flash Distillation Introduction to Vapor-Liquid Equilibrium VLE in ideal mixtures VLE in non-ideal mixtures Flash Distillation 作業 HW 6 6% 15 CHEMICAL EQUILIBRIUM Single-reaction chemical equilibrium in single-phase system multi-reaction chemical equilibrium in single-phase system Ionization and acidity of solutions Partition of amino acids and proteins between two liquids Single-reaction chemical equilibrium in single-phase system multi-reaction chemical equilibrium in single-phase system Ionization and acidity of solutions Partition of amino acids and proteins between two liquids 16 FINAL EXAM Final exam Final exam 期末考 Final exam 30% 17 ASPEN PROJECT 1 Chemical reaction equilibrium Learn how to use Aspen to calculate chemical reaction equilibrium 實作 彈性教學 Aspen design report 1 5% 18 ASPEN PROJECT 2 phase equilibrium calculation Learn how to use Aspen to calculate phase equilibrium 實作 彈性教學 Aspen design report 2 5%

 序No. 實施期間Period 實施方式Content 教學說明Teaching instructions 彈性教學評量方式Evaluation 備註Notes 1 起:2024-06-11 迄:2024-06-12 ASPEN PROJECT 1: Chemical reaction equilibrium ASPEN PROJECT 1 design report 2 起:2024-06-18 迄:2024-06-19 ASPEN PROJECT 2: Phase equilibrium ASPEN PROJECT 2 design report

 教學要點概述： 1.自編教材 Handout by Instructor： □ 1-1.簡報 Slids □ 1-2.影音教材 Videos □ 1-3.教具 Teaching Aids ■ 1-4.教科書 Textbook ■ 1-5.其他 Other □ 2.自編評量工具/量表 Educational Assessment □ 3.教科書作者提供 Textbook 成績考核 Performance Evaluation： 作業：30%   期中考：30%   期末考：30%   彈性教學：10%   教學資源(Teaching Resources)： □ 教材電子檔(Soft Copy of the Handout or the Textbook) □ 課程網站(Website) 扣考規定：https://curri.ttu.edu.tw/p/412-1033-1254.php