教學大綱表 Syllabus
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課程名稱
Course Title		 (中文) 高等高分子科學
(英文) Advanced Polymer Science 		開課單位
Departments		 化學工程與生物科技研究所
課程代碼
Course No.		 C6090
授課教師
Instructor		 黃繼遠
學分數
Credit		 3.0 必/選修
core required/optional		 選修 開課年級
Level		 研究所
先修科目或先備能力Course Pre-requisites：Organic chemistry and Polymer Chemistry
課程概述與目標 Course Overview and Goals： 本課程主要讓同學瞭解高分子化學相關領域之專業知識與能力, 以及能夠自行研讀高分子期刊之能力, 達成永續學習之教育目標。
其主要授與內容為 I.Free-Radical Chain-Growth Polymerization, II. Step Growth Polymerization, III. Ionic Chain-Growth Polymerization, 及 IV Polymer Properties.
教科書
Textbook		 Book title: Principles of Polymer Chemistry
Book version: 2nd Edition
Author: A. Ravve
Book Agent: (科大)
參考教材
Reference		 Book title: Polymer Chemistry - an Introduction
Book version: 3rd Edition
Author: Malcom P. Stevens
Book Agent: (高立)
課程大綱
Syllabus		 學生學習目標
Learning Objectives		 單元學習活動
Learning Activities		 學習成效評量
Evaluation		 備註
Notes
週
Week		 單元主題
Unit topic		 內容綱要
Content summary
1 Basic Principles 1. Definitions
2. Polymerization Processes
3. Chain reaction Polymerization
4. Step-reaction Polymerization 		1. Definitions
2. Polymerization Processes
3. Chain reaction Polymerization
4. Step-reaction Polymerization
  • 講授
    •      		 
    2 Free-Radical Chain-Growth Polymerization I 1. Free-Radical Chain-Growth Polymerization Process
    2. Capture of the Free Radical by the Monomers
    3. Propagation
    4. Termination Reaction
    5. Copolymerization
    6. Inhibition and Retardation     		1. Free-Radical Chain-Growth Polymerization Process
    2. Capture of the Free Radical by the Monomers
    3. Propagation
    4. Termination Reaction
    5. Copolymerization
    6. Inhibition and Retardation
  • 講授
    •
  • 作業 Assignment
    •      		 
    3 Free-Radical Chain-Growth Polymerization I 1.Free-Radical Chain-Growth Polymerization Process
    2.Capture of the Free Radical by the Monomers
    3.Propagation
    4.Termination Reaction
    5.Copolymerization
    6.Inhibition and Retardation     		1.Free-Radical Chain-Growth Polymerization Process
    2.Capture of the Free Radical by the Monomers
    3.Propagation
    4.Termination Reaction
    5.Copolymerization
    6.Inhibition and Retardation
  • 講授
    •      		 
    4 Free-Radical Chain-Growth Polymerization II 7.Donor-Acceptor Complexes in Copolymerization
    8. Polymerization of Complexes With Lewis Acids
    9. Controlled/"Living" Polymerization
    10. Atom Transfer Radical Polymerization
    11. Kinetic of Controlled/ “Living” Polymerization     		7.Donor-Acceptor Complexes in Copolymerization
    8. Polymerization of Complexes With Lewis Acids
    9. Controlled/"Living" Polymerization
    10. Atom Transfer Radical Polymerization
    11. Kinetic of Controlled/ "Living" Polymerization
  • 講授
    •
  • 作業 Assignment
    •      		 
    5 Free-Radical Chain-Growth Polymerization II 7.Donor-Acceptor Complexes in Copolymerization
    8. Polymerization of Complexes With Lewis Acids
    9. Controlled/”Living” Polymerization
    10. Atom Transfer Radical Polymerization
    11. Kinetic of Controlled/ “Living” Polymerization     		7.Donor-Acceptor Complexes in Copolymerization
    8. Polymerization of Complexes With Lewis Acids
    9. Controlled/”Living” Polymerization
    10. Atom Transfer Radical Polymerization
    11. Kinetic of Controlled/ “Living” Polymerization
  • 講授
    •
  • 作業 Assignment
    •      		 
    6 Ionic Chain-Growth Polymerization 1 Chemistry of Ionic Chain-Growth Polymerization
    2 Kinetic of ionic Chain Growth Polymerization
    3 Cationic Polymerization
    4 Anionic Polymerization of Olefins     		1 Chemistry of Ionic Chain-Growth Polymerization
    2 Kinetic of ionic Chain Growth Polymerization
    3 Cationic Polymerization
    4 Anionic Polymerization of Olefins
  • 講授
    •
  • 作業 Assignment
    •      		 
    7 Step Growth Polymerization (I-1) 1 Mechanism and Kinetics of Step Growth Polymerization
    2 Polyesters
    3 Polyamides
    4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
    5 Polyimides
    6 Polyethers     		1 Mechanism and Kinetics of Step Growth Polymerization
    2 Polyesters
    3 Polyamides
    4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
    5 Polyimides
    6 Polyethers
  • 講授
    •      		 
    8 Step Growth Polymerization (I-2) 1 Mechanism and Kinetics of Step Growth Polymerization
    2 Polyesters
    3 Polyamides
    4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
    5 Polyimides
    6 Polyethers     		1 Mechanism and Kinetics of Step Growth Polymerization
    2 Polyesters
    3 Polyamides
    4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
    5 Polyimides
    6 Polyethers
  • 講授
    •
  • 作業 Assignment
    •      		 
    9 Step Growth Polymerization (I-3) 1 Mechanism and Kinetics of Step Growth Polymerization
    2 Polyesters
    3 Polyamides
    4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
    5 Polyimides
    6 Polyethers     		1 Mechanism and Kinetics of Step Growth Polymerization
    2 Polyesters
    3 Polyamides
    4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
    5 Polyimides
    6 Polyethers
  • 講授
    •
  • 期中考 Midterm
    •      		期中考週  
    10 Step Growth Polymerization (II-1) 7 Polyurethanes
    8 Epoxy Resins
    9 Phenol-Formaldehyde Resins
    10 Silicon Polymers
    11 High Performance Polymers
    12 Dendrimers and Polyrotaxanes     		7 Polyurethanes
    8 Epoxy Resins
    9 Phenol-Formaldehyde Resins
    10 Silicon Polymers
    11 High Performance Polymers
    12 Dendrimers and Polyrotaxanes
  • 講授
    •      		 
    11 Step Growth Polymerization (II-2) 7 Polyurethanes
    8 Epoxy Resins
    9 Phenol-Formaldehyde Resins
    10 Silicon Polymers
    11 High Performance Polymers
    12 Dendrimers and Polyrotaxanes     		7 Polyurethanes
    8 Epoxy Resins
    9 Phenol-Formaldehyde Resins
    10 Silicon Polymers
    11 High Performance Polymers
    12 Dendrimers and Polyrotaxanes
  • 講授
    •
  • 作業 Assignment
    •      		 
    12 Molecular Weight and Polymer Solution (I) 1.Number average(Mn) and weight average(Mw) molecular weight
    2.Polymer solution
    3.Measurement of Mn and Mw
    4.Viscometry
    5.Molecular Distribution     		1.Number average(Mn) and weight average(Mw) molecular weight
    2.Polymer solution
    3.Measurement of Mn and Mw
    4.Viscometry
    5.Molecular Distribution
  • 講授
    •      		 
    13 Molecular Weight and Polymer Solution (II) 1.Number average(Mn) and weight average(Mw) molecular weight
    2.Polymer solution
    3.Measurement of Mn and Mw
    4.Viscometry
    5.Molecular Distribution     		1.Number average(Mn) and weight average(Mw) molecular weight
    2.Polymer solution
    3.Measurement of Mn and Mw
    4.Viscometry
    5.Molecular Distribution
  • 講授
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  • 作業 Assignment
    •      		 
    14 Chemical Structure and Polymer Morphology 1.Molecular weight and intermolecular forces
    2. Rheology
    3. Glass transition temperature
    4. Crosslinking
    5.Polymer Blend     		1.Molecular weight and intermolecular forces
    2. Rheology
    3. Glass transition temperature
    4. Crosslinking
    5.Polymer Blend
  • 講授
    •      		 
    15 Chemical Structure and Polymer Properties 1.Mechanical Properties
    2.Thermal Stability
    3.Flammability
    4.Degradability     		1.Mechanical Properties
    2.Thermal Stability
    3.Flammability
    4.Degradability
  • 講授
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  • 作業 Assignment
    •      		 
    16 Mechanical Properties at Small Deformation I 1. Elasticity in various geometry
    2. Rubber elasticity
    3. Viscoelasticity- Maxwell Model
    4. Master Curve     		讓學生學習到 Viscoelasticity- Maxwell Model
  • 講授
    •      		 
    17 Mechanical Properties at Small Deformation I 1. Elasticity in various geometry
    2. Rubber elasticity
    3. Viscoelasticity- Maxwell Model
    4. Master Curve     		讓學生學習到 Viscoelasticity- Maxwell Model
  • 講授
    •
  • 作業 Assignment
    •      		 
    18 總複習 總複習 總複習
  • 期末考 Final Exam
    •      		期末考週  

    教學要點概述 Overview of Teaching Points：
    教材編選 Teaching Materials： □ 自編教材 Handout by Instructor ■ 教科書作者提供 Textbook
    評量方法 Evaluation： 期末考 Final Exam：30%   期中考 Midterm：30%   報告 Presentation：10%   平時考 Test：20%   作業 Assignment：10%  
    教學資源 Teaching Resources： □ 教材電子檔 Soft Copy of the Handout or the Textbook □ 課程網站 Website
    扣考規定 The rule of being able to take the final exam of the course：http://eboard.ttu.edu.tw/ttuwebpost/showcontent-news.php?id=504