課程名稱 |
(中文) 高等高分子科學 (英文) Advanced Polymer Science |
開課單位 | 化學工程與生物科技研究所 | ||
課程代碼 | C6090 | ||||
授課教師 | 黃繼遠 | ||||
學分數 | 3.0 | 必/選修 | 選修 | 開課年級 | 研究所 |
先修科目或先備能力:Organic chemistry and Polymer Chemistry | |||||
課程概述與目標: 本課程主要讓同學瞭解高分子化學相關領域之專業知識與能力, 以及能夠自行研讀高分子期刊之能力, 達成永續學習之教育目標。 其主要授與內容為 I.Free-Radical Chain-Growth Polymerization, II. Step Growth Polymerization, III. Ionic Chain-Growth Polymerization, 及 IV Polymer Properties. | |||||
教科書 | Book title: Principles of Polymer Chemistry Book version: 2nd Edition Author: A. Ravve Book Agent: (科大) |
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參考教材 | Book title: Polymer Chemistry - an Introduction Book version: 3rd Edition Author: Malcom P. Stevens Book Agent: (高立) |
課程大綱 | 學生學習目標 | 單元學習活動 | 學習成效評量 | 備註 | ||
週 | 單元主題 | 內容綱要 | ||||
1 | Basic Principles | 1. Definitions 2. Polymerization Processes 3. Chain reaction Polymerization 4. Step-reaction Polymerization |
1. Definitions 2. Polymerization Processes 3. Chain reaction Polymerization 4. Step-reaction Polymerization |
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2 | Free-Radical Chain-Growth Polymerization I | 1. Free-Radical Chain-Growth Polymerization Process 2. Capture of the Free Radical by the Monomers 3. Propagation 4. Termination Reaction 5. Copolymerization 6. Inhibition and Retardation |
1. Free-Radical Chain-Growth Polymerization Process 2. Capture of the Free Radical by the Monomers 3. Propagation 4. Termination Reaction 5. Copolymerization 6. Inhibition and Retardation |
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3 | Free-Radical Chain-Growth Polymerization I | 1.Free-Radical Chain-Growth Polymerization Process 2.Capture of the Free Radical by the Monomers 3.Propagation 4.Termination Reaction 5.Copolymerization 6.Inhibition and Retardation |
1.Free-Radical Chain-Growth Polymerization Process 2.Capture of the Free Radical by the Monomers 3.Propagation 4.Termination Reaction 5.Copolymerization 6.Inhibition and Retardation |
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4 | Free-Radical Chain-Growth Polymerization II | 7.Donor-Acceptor Complexes in Copolymerization 8. Polymerization of Complexes With Lewis Acids 9. Controlled/"Living" Polymerization 10. Atom Transfer Radical Polymerization 11. Kinetic of Controlled/ “Living” Polymerization |
7.Donor-Acceptor Complexes in Copolymerization 8. Polymerization of Complexes With Lewis Acids 9. Controlled/"Living" Polymerization 10. Atom Transfer Radical Polymerization 11. Kinetic of Controlled/ "Living" Polymerization |
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5 | Free-Radical Chain-Growth Polymerization II | 7.Donor-Acceptor Complexes in Copolymerization 8. Polymerization of Complexes With Lewis Acids 9. Controlled/”Living” Polymerization 10. Atom Transfer Radical Polymerization 11. Kinetic of Controlled/ “Living” Polymerization |
7.Donor-Acceptor Complexes in Copolymerization 8. Polymerization of Complexes With Lewis Acids 9. Controlled/”Living” Polymerization 10. Atom Transfer Radical Polymerization 11. Kinetic of Controlled/ “Living” Polymerization |
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6 | Ionic Chain-Growth Polymerization | 1 Chemistry of Ionic Chain-Growth Polymerization 2 Kinetic of ionic Chain Growth Polymerization 3 Cationic Polymerization 4 Anionic Polymerization of Olefins |
1 Chemistry of Ionic Chain-Growth Polymerization 2 Kinetic of ionic Chain Growth Polymerization 3 Cationic Polymerization 4 Anionic Polymerization of Olefins |
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7 | Step Growth Polymerization (I-1) | 1 Mechanism and Kinetics of Step Growth Polymerization 2 Polyesters 3 Polyamides 4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides 5 Polyimides 6 Polyethers |
1 Mechanism and Kinetics of Step Growth Polymerization 2 Polyesters 3 Polyamides 4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides 5 Polyimides 6 Polyethers |
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8 | Step Growth Polymerization (I-2) | 1 Mechanism and Kinetics of Step Growth Polymerization 2 Polyesters 3 Polyamides 4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides 5 Polyimides 6 Polyethers |
1 Mechanism and Kinetics of Step Growth Polymerization 2 Polyesters 3 Polyamides 4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides 5 Polyimides 6 Polyethers |
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9 | Step Growth Polymerization (I-3) | 1 Mechanism and Kinetics of Step Growth Polymerization 2 Polyesters 3 Polyamides 4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides 5 Polyimides 6 Polyethers |
1 Mechanism and Kinetics of Step Growth Polymerization 2 Polyesters 3 Polyamides 4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides 5 Polyimides 6 Polyethers |
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期中考週 |
10 | Step Growth Polymerization (II-1) | 7 Polyurethanes 8 Epoxy Resins 9 Phenol-Formaldehyde Resins 10 Silicon Polymers 11 High Performance Polymers 12 Dendrimers and Polyrotaxanes |
7 Polyurethanes 8 Epoxy Resins 9 Phenol-Formaldehyde Resins 10 Silicon Polymers 11 High Performance Polymers 12 Dendrimers and Polyrotaxanes |
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11 | Step Growth Polymerization (II-2) | 7 Polyurethanes 8 Epoxy Resins 9 Phenol-Formaldehyde Resins 10 Silicon Polymers 11 High Performance Polymers 12 Dendrimers and Polyrotaxanes |
7 Polyurethanes 8 Epoxy Resins 9 Phenol-Formaldehyde Resins 10 Silicon Polymers 11 High Performance Polymers 12 Dendrimers and Polyrotaxanes |
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12 | Molecular Weight and Polymer Solution (I) | 1.Number average(Mn) and weight average(Mw) molecular weight 2.Polymer solution 3.Measurement of Mn and Mw 4.Viscometry 5.Molecular Distribution |
1.Number average(Mn) and weight average(Mw) molecular weight 2.Polymer solution 3.Measurement of Mn and Mw 4.Viscometry 5.Molecular Distribution |
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13 | Molecular Weight and Polymer Solution (II) | 1.Number average(Mn) and weight average(Mw) molecular weight 2.Polymer solution 3.Measurement of Mn and Mw 4.Viscometry 5.Molecular Distribution |
1.Number average(Mn) and weight average(Mw) molecular weight 2.Polymer solution 3.Measurement of Mn and Mw 4.Viscometry 5.Molecular Distribution |
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14 | Chemical Structure and Polymer Morphology | 1.Molecular weight and intermolecular forces 2. Rheology 3. Glass transition temperature 4. Crosslinking 5.Polymer Blend |
1.Molecular weight and intermolecular forces 2. Rheology 3. Glass transition temperature 4. Crosslinking 5.Polymer Blend |
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15 | Chemical Structure and Polymer Properties | 1.Mechanical Properties 2.Thermal Stability 3.Flammability 4.Degradability |
1.Mechanical Properties 2.Thermal Stability 3.Flammability 4.Degradability |
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16 | Mechanical Properties at Small Deformation I | 1. Elasticity in various geometry 2. Rubber elasticity 3. Viscoelasticity- Maxwell Model 4. Master Curve |
讓學生學習到 Viscoelasticity- Maxwell Model |
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17 | Mechanical Properties at Small Deformation I | 1. Elasticity in various geometry 2. Rubber elasticity 3. Viscoelasticity- Maxwell Model 4. Master Curve |
讓學生學習到 Viscoelasticity- Maxwell Model |
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18 | 總複習 | 總複習 | 總複習 |
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期末考週 |
教學要點概述: |