教學大綱表 (111學年度 第1學期)
請遵守智慧財產權,勿使用非法影印教科書,避免觸法。
課程名稱
Course Title
(中文) 高等高分子科學
(英文) Advanced Polymer Science
開課單位
Departments
化學工程與生物科技研究所
課程代碼
Course No.
C6090
授課教師
Instructor
黃繼遠
學分數
Credit
3.0 必/選修
core required/optional
選修 開課年級
Level
研究所
先修科目或先備能力(Course Pre-requisites):Organic chemistry and Polymer Chemistry
課程概述與目標(Course Overview and Goals): 本課程主要讓同學瞭解高分子化學相關領域之專業知識與能力, 以及能夠自行研讀高分子期刊之能力, 達成永續學習之教育目標。
其主要授與內容為 I.Free-Radical Chain-Growth Polymerization, II. Step Growth Polymerization, III. Ionic Chain-Growth Polymerization, 及 IV Polymer Properties.
教科書(Textbook) Book title: Principles of Polymer Chemistry
Book version: 2nd Edition
Author: A. Ravve
Book Agent: (科大)
參考教材(Reference) Book title: Polymer Chemistry - an Introduction
Book version: 3rd Edition
Author: Malcom P. Stevens
Book Agent: (高立)
課程大綱 Syllabus 學生學習目標
Learning Objectives
單元學習活動
Learning Activities
學習成效評量
Evaluation
備註
Notes

No.
單元主題
Unit topic
內容綱要
Content summary
1 Basic Principles 1. Definitions
2. Polymerization Processes
3. Chain reaction Polymerization
4. Step-reaction Polymerization
1. Definitions
2. Polymerization Processes
3. Chain reaction Polymerization
4. Step-reaction Polymerization
 
2 Free-Radical Chain-Growth Polymerization I 1. Free-Radical Chain-Growth Polymerization Process
2. Capture of the Free Radical by the Monomers
3. Propagation
4. Termination Reaction
5. Copolymerization
6. Inhibition and Retardation
1. Free-Radical Chain-Growth Polymerization Process
2. Capture of the Free Radical by the Monomers
3. Propagation
4. Termination Reaction
5. Copolymerization
6. Inhibition and Retardation
 
3 Free-Radical Chain-Growth Polymerization I 1.Free-Radical Chain-Growth Polymerization Process
2.Capture of the Free Radical by the Monomers
3.Propagation
4.Termination Reaction
5.Copolymerization
6.Inhibition and Retardation
1.Free-Radical Chain-Growth Polymerization Process
2.Capture of the Free Radical by the Monomers
3.Propagation
4.Termination Reaction
5.Copolymerization
6.Inhibition and Retardation
 
4 Free-Radical Chain-Growth Polymerization II 7.Donor-Acceptor Complexes in Copolymerization
8. Polymerization of Complexes With Lewis Acids
9. Controlled/"Living" Polymerization
10. Atom Transfer Radical Polymerization
11. Kinetic of Controlled/ “Living” Polymerization
7.Donor-Acceptor Complexes in Copolymerization
8. Polymerization of Complexes With Lewis Acids
9. Controlled/"Living" Polymerization
10. Atom Transfer Radical Polymerization
11. Kinetic of Controlled/ "Living" Polymerization
 
5 Free-Radical Chain-Growth Polymerization II 7.Donor-Acceptor Complexes in Copolymerization
8. Polymerization of Complexes With Lewis Acids
9. Controlled/”Living” Polymerization
10. Atom Transfer Radical Polymerization
11. Kinetic of Controlled/ “Living” Polymerization
7.Donor-Acceptor Complexes in Copolymerization
8. Polymerization of Complexes With Lewis Acids
9. Controlled/”Living” Polymerization
10. Atom Transfer Radical Polymerization
11. Kinetic of Controlled/ “Living” Polymerization
 
6 Ionic Chain-Growth Polymerization 1 Chemistry of Ionic Chain-Growth Polymerization
2 Kinetic of ionic Chain Growth Polymerization
3 Cationic Polymerization
4 Anionic Polymerization of Olefins
1 Chemistry of Ionic Chain-Growth Polymerization
2 Kinetic of ionic Chain Growth Polymerization
3 Cationic Polymerization
4 Anionic Polymerization of Olefins
 
7 Step Growth Polymerization (I-1) 1 Mechanism and Kinetics of Step Growth Polymerization
2 Polyesters
3 Polyamides
4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
5 Polyimides
6 Polyethers
1 Mechanism and Kinetics of Step Growth Polymerization
2 Polyesters
3 Polyamides
4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
5 Polyimides
6 Polyethers
 
8 Step Growth Polymerization (I-2) 1 Mechanism and Kinetics of Step Growth Polymerization
2 Polyesters
3 Polyamides
4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
5 Polyimides
6 Polyethers
1 Mechanism and Kinetics of Step Growth Polymerization
2 Polyesters
3 Polyamides
4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
5 Polyimides
6 Polyethers
 
9 Step Growth Polymerization (I-3) 1 Mechanism and Kinetics of Step Growth Polymerization
2 Polyesters
3 Polyamides
4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
5 Polyimides
6 Polyethers
1 Mechanism and Kinetics of Step Growth Polymerization
2 Polyesters
3 Polyamides
4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
5 Polyimides
6 Polyethers
期中考週  
10 Step Growth Polymerization (II-1) 7 Polyurethanes
8 Epoxy Resins
9 Phenol-Formaldehyde Resins
10 Silicon Polymers
11 High Performance Polymers
12 Dendrimers and Polyrotaxanes
7 Polyurethanes
8 Epoxy Resins
9 Phenol-Formaldehyde Resins
10 Silicon Polymers
11 High Performance Polymers
12 Dendrimers and Polyrotaxanes
 
11 Step Growth Polymerization (II-2) 7 Polyurethanes
8 Epoxy Resins
9 Phenol-Formaldehyde Resins
10 Silicon Polymers
11 High Performance Polymers
12 Dendrimers and Polyrotaxanes
7 Polyurethanes
8 Epoxy Resins
9 Phenol-Formaldehyde Resins
10 Silicon Polymers
11 High Performance Polymers
12 Dendrimers and Polyrotaxanes
 
12 Molecular Weight and Polymer Solution (I) 1.Number average(Mn) and weight average(Mw) molecular weight
2.Polymer solution
3.Measurement of Mn and Mw
4.Viscometry
5.Molecular Distribution
1.Number average(Mn) and weight average(Mw) molecular weight
2.Polymer solution
3.Measurement of Mn and Mw
4.Viscometry
5.Molecular Distribution
 
13 Molecular Weight and Polymer Solution (II) 1.Number average(Mn) and weight average(Mw) molecular weight
2.Polymer solution
3.Measurement of Mn and Mw
4.Viscometry
5.Molecular Distribution
1.Number average(Mn) and weight average(Mw) molecular weight
2.Polymer solution
3.Measurement of Mn and Mw
4.Viscometry
5.Molecular Distribution
 
14 Chemical Structure and Polymer Morphology 1.Molecular weight and intermolecular forces
2. Rheology
3. Glass transition temperature
4. Crosslinking
5.Polymer Blend
1.Molecular weight and intermolecular forces
2. Rheology
3. Glass transition temperature
4. Crosslinking
5.Polymer Blend
 
15 Chemical Structure and Polymer Properties 1.Mechanical Properties
2.Thermal Stability
3.Flammability
4.Degradability
1.Mechanical Properties
2.Thermal Stability
3.Flammability
4.Degradability
 
16 Mechanical Properties at Small Deformation I 1. Elasticity in various geometry
2. Rubber elasticity
3. Viscoelasticity- Maxwell Model
4. Master Curve
讓學生學習到 Viscoelasticity- Maxwell Model  
17 Mechanical Properties at Small Deformation I 1. Elasticity in various geometry
2. Rubber elasticity
3. Viscoelasticity- Maxwell Model
4. Master Curve
讓學生學習到 Viscoelasticity- Maxwell Model  
18 總複習 總複習 總複習 期末考週  


教學要點概述:
教材編選(Teaching Materials):
□ 1-1.簡報 Slids
□ 1-2.影音教材 Videos
□ 1-3.教具 Teaching Aids
□ 1-4.教科書 Textbook Slids
□ 1-5.其他 Other
□ 2.自編評量工具/量表 Educational Assessment
□ 3.教科書作者提供 Textbook

成績考核 Performance Evaluation: 期末考:30%   期中考:30%   報告:10%   平時考:20%   作業:10%  

教學資源(Teaching Resources):
□ 教材電子檔(Soft Copy of the Handout or the Textbook)
□ 課程網站(Website)
扣考規定:http://eboard.ttu.edu.tw/ttuwebpost/showcontent-news.php?id=504