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課程名稱 (中文) 高等高分子科學
(英文) Advanced Polymer Science
開課單位 化學工程研究所
課程代碼 C6090
授課教師 龔宇睿
學分數 3.0 必/選修 選修 開課年級 研究所
先修科目或先備能力:Organic chemistry and Polymer Chemistry
課程概述與目標: 本課程主要讓同學瞭解高分子化學相關領域之專業知識與能力, 以及能夠自行研讀高分子期刊之能力, 達成永續學習之教育目標。
其主要授與內容為 I.Free-Radical Chain-Growth Polymerization, II. Step Growth Polymerization, III. Ionic Chain-Growth Polymerization, 及 IV Polymer Properties.
教科書 Book title: Principles of Polymer Chemistry
Book version: 2nd Edition
Author: A. Ravve
Book Agent: (科大)
參考教材 Book title: Polymer Chemistry - an Introduction
Book version: 3rd Edition
Author: Malcom P. Stevens
Book Agent: (高立)
課程大綱 學生學習目標 單元學習活動 學習成效評量 備註
單元主題 內容綱要
1 Basic Principles 1. Definitions
2. Polymerization Processes
3. Chain reaction Polymerization
4. Step-reaction Polymerization
1. Definitions
2. Polymerization Processes
3. Chain reaction Polymerization
4. Step-reaction Polymerization
  • 講授
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    2 Free-Radical Chain-Growth Polymerization I 1. Free-Radical Chain-Growth Polymerization Process
    2. Capture of the Free Radical by the Monomers
    3. Propagation
    4. Termination Reaction
    5. Copolymerization
    6. Inhibition and Retardation
    1. Free-Radical Chain-Growth Polymerization Process
    2. Capture of the Free Radical by the Monomers
    3. Propagation
    4. Termination Reaction
    5. Copolymerization
    6. Inhibition and Retardation
  • 講授
  • 作業
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    3 Free-Radical Chain-Growth Polymerization I 1.Free-Radical Chain-Growth Polymerization Process
    2.Capture of the Free Radical by the Monomers
    3.Propagation
    4.Termination Reaction
    5.Copolymerization
    6.Inhibition and Retardation
    1.Free-Radical Chain-Growth Polymerization Process
    2.Capture of the Free Radical by the Monomers
    3.Propagation
    4.Termination Reaction
    5.Copolymerization
    6.Inhibition and Retardation
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    4 Free-Radical Chain-Growth Polymerization II 7.Donor-Acceptor Complexes in Copolymerization
    8. Polymerization of Complexes With Lewis Acids
    9. Controlled/"Living" Polymerization
    10. Atom Transfer Radical Polymerization
    11. Kinetic of Controlled/ “Living” Polymerization
    7.Donor-Acceptor Complexes in Copolymerization
    8. Polymerization of Complexes With Lewis Acids
    9. Controlled/"Living" Polymerization
    10. Atom Transfer Radical Polymerization
    11. Kinetic of Controlled/ "Living" Polymerization
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  • 作業
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    5 Free-Radical Chain-Growth Polymerization II 7.Donor-Acceptor Complexes in Copolymerization
    8. Polymerization of Complexes With Lewis Acids
    9. Controlled/”Living” Polymerization
    10. Atom Transfer Radical Polymerization
    11. Kinetic of Controlled/ “Living” Polymerization
    7.Donor-Acceptor Complexes in Copolymerization
    8. Polymerization of Complexes With Lewis Acids
    9. Controlled/”Living” Polymerization
    10. Atom Transfer Radical Polymerization
    11. Kinetic of Controlled/ “Living” Polymerization
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  • 作業
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    6 Ionic Chain-Growth Polymerization 1 Chemistry of Ionic Chain-Growth Polymerization
    2 Kinetic of ionic Chain Growth Polymerization
    3 Cationic Polymerization
    4 Anionic Polymerization of Olefins
    1 Chemistry of Ionic Chain-Growth Polymerization
    2 Kinetic of ionic Chain Growth Polymerization
    3 Cationic Polymerization
    4 Anionic Polymerization of Olefins
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  • 作業
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    7 Step Growth Polymerization (I-1) 1 Mechanism and Kinetics of Step Growth Polymerization
    2 Polyesters
    3 Polyamides
    4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
    5 Polyimides
    6 Polyethers
    1 Mechanism and Kinetics of Step Growth Polymerization
    2 Polyesters
    3 Polyamides
    4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
    5 Polyimides
    6 Polyethers
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    8 Step Growth Polymerization (I-2) 1 Mechanism and Kinetics of Step Growth Polymerization
    2 Polyesters
    3 Polyamides
    4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
    5 Polyimides
    6 Polyethers
    1 Mechanism and Kinetics of Step Growth Polymerization
    2 Polyesters
    3 Polyamides
    4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
    5 Polyimides
    6 Polyethers
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  • 作業
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    9 Step Growth Polymerization (I-3) 1 Mechanism and Kinetics of Step Growth Polymerization
    2 Polyesters
    3 Polyamides
    4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
    5 Polyimides
    6 Polyethers
    1 Mechanism and Kinetics of Step Growth Polymerization
    2 Polyesters
    3 Polyamides
    4 Aromatic Polyamide-Imides and Aromatic Polyester-Imides
    5 Polyimides
    6 Polyethers
  • 講授
  • 期中考
  • 期中考週  
    10 Step Growth Polymerization (II-1) 7 Polyurethanes
    8 Epoxy Resins
    9 Phenol-Formaldehyde Resins
    10 Silicon Polymers
    11 High Performance Polymers
    12 Dendrimers and Polyrotaxanes
    7 Polyurethanes
    8 Epoxy Resins
    9 Phenol-Formaldehyde Resins
    10 Silicon Polymers
    11 High Performance Polymers
    12 Dendrimers and Polyrotaxanes
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    11 Step Growth Polymerization (II-2) 7 Polyurethanes
    8 Epoxy Resins
    9 Phenol-Formaldehyde Resins
    10 Silicon Polymers
    11 High Performance Polymers
    12 Dendrimers and Polyrotaxanes
    7 Polyurethanes
    8 Epoxy Resins
    9 Phenol-Formaldehyde Resins
    10 Silicon Polymers
    11 High Performance Polymers
    12 Dendrimers and Polyrotaxanes
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  • 作業
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    12 Molecular Weight and Polymer Solution (I) 1.Number average(Mn) and weight average(Mw) molecular weight
    2.Polymer solution
    3.Measurement of Mn and Mw
    4.Viscometry
    5.Molecular Distribution
    1.Number average(Mn) and weight average(Mw) molecular weight
    2.Polymer solution
    3.Measurement of Mn and Mw
    4.Viscometry
    5.Molecular Distribution
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    13 Molecular Weight and Polymer Solution (II) 1.Number average(Mn) and weight average(Mw) molecular weight
    2.Polymer solution
    3.Measurement of Mn and Mw
    4.Viscometry
    5.Molecular Distribution
    1.Number average(Mn) and weight average(Mw) molecular weight
    2.Polymer solution
    3.Measurement of Mn and Mw
    4.Viscometry
    5.Molecular Distribution
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  • 作業
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    14 Chemical Structure and Polymer Morphology 1.Molecular weight and intermolecular forces
    2. Rheology
    3. Glass transition temperature
    4. Crosslinking
    5.Polymer Blend
    1.Molecular weight and intermolecular forces
    2. Rheology
    3. Glass transition temperature
    4. Crosslinking
    5.Polymer Blend
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    15 Chemical Structure and Polymer Properties 1.Mechanical Properties
    2.Thermal Stability
    3.Flammability
    4.Degradability
    1.Mechanical Properties
    2.Thermal Stability
    3.Flammability
    4.Degradability
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    16 Mechanical Properties at Small Deformation I 1. Elasticity in various geometry
    2. Rubber elasticity
    3. Viscoelasticity- Maxwell Model
    4. Master Curve
    讓學生學習到 Viscoelasticity- Maxwell Model
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    17 Mechanical Properties at Small Deformation I 1. Elasticity in various geometry
    2. Rubber elasticity
    3. Viscoelasticity- Maxwell Model
    4. Master Curve
    讓學生學習到 Viscoelasticity- Maxwell Model
  • 講授
  • 作業
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    18 總複習 總複習 總複習
  • 期末考
  • 期末考週  

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