課程名稱Course Title (中文) 高等化工熱力學 (英文) Advanced Chemical Engineering Thermodynamics 開課單位Departments 化學工程與生物科技研究所 課程代碼Course No. C6100 授課教師Instructor 陳嘉明 學分數Credit 3.0 必/選修core required/optional 選修 開課年級Level 研究所 先修科目或先備能力(Course Pre-requisites)：Chemical engineering thermodynamics 課程概述與目標(Course Overview and Goals)：This course starts with reviewing the topics taught in undergraduate course, including mass balance, energy balance, heat-work transformation, real gas thermodynamic property calculations, single component phase equilibrium. Then extend to mixture thermodynamic properties, solution activity coefficient models, chemical reaction equilibrium calculations, and adsorption thermodynamics will be taught to meet students’ research’s need. 教科書(Textbook) Stanley I. Sandler, " Chemical, Biochemical, and Engineering Thermodynamics," 4th ed., John Wiley & Sons, 2006 參考教材(Reference) 1. Aspen Plus User Manual. 2. Prausnitz, J. M., et al., Molecular Thermodynamics of Fluid-Phase Equilibria, 3rd ed., Prentice-Hall, NJ, 1999. 圖書館電子書(E-book of the Library) Ingo Muller and Wolfgang H. Muller Fundamentals of Thermodynamics and Applications Springer, 2009, ISBN 978-3-540-74645-4, e-ISBN 978-3-540-74648-5
 課程大綱 Syllabus 學生學習目標Learning Objectives 單元學習活動Learning Activities 學習成效評量Evaluation 備註Notes 序No. 單元主題Unit topic 內容綱要Content summary 1 Introduction 1. The Equilibrium State 2. Intensive and Extensive Variables 3. Important Thermodynamic Terms 1. The Equilibrium State 2. Intensive and Extensive Variables 3. Important Thermodynamic Terms 講授 2 Review of classical thermodynamics First law of thermodynamics To learn the principle and applications of the first law of thermodynamics 講授 作業 HW 1 5% 3 Review of classical thermodynamics second law of thermodynamics To learn the principle and applications of the second law of thermodynamics 講授 作業 HW 2 5% 4 The Calculus of Thermodynamics The Calculus of Thermodynamics To learn the fundamental mathematics related to thermodynamics 講授 5 Thermodynamic Properties of Fluids 1. Some Mathematical Prelimilaries 2. Thermodynamic Partial Derivatives 3. Euation of States 1. Some Mathematical Prelimilaries 2. Thermodynamic Partial Derivatives 3. Euation of States 講授 6 Thermodynamic Properties of Fluids 1. Principle of Corresponding States 2. Calculation of Thermodynamic Properties by Equation of States 1. Principle of Corresponding States 2. Calculation of Thermodynamic Properties by Equation of States 講授 作業 HW 3 5% 7 Chemical Reaction Equilibrium 1. Chemical Equilibrium 2. Hetrogeneous Chemical Reactios 3. Combined Chemical and Phase Equilibria 1. Chemical Equilibrium 2. Hetrogeneous Chemical Reactios 3. Combined Chemical and Phase Equilibria 講授 作業 HW 4 5% 8 Mid-Term Exam Exam Covering Those Taught in the First 7 Weeks Review of Those Taught in the First 7 Weeks 期中考 Midterm exam. 20% 9 Phase Equilibrium 1. Equilibrium Criteria 2. Stability of Thermodynamic Systems 3. Calculation of Vapor Pressure by Equation of State 1. Equilibrium Criteria 2. Stability of Thermodynamic Systems 3. Calculation of Vapor Pressure by Equation of State. 講授 作業 HW 5 5% 10 Phase Equilibrium 1. The Gibbs Phase Rule 2. Thermodynamic Properties of Phase Transitions 1. The Gibbs Phase Rule 2. Thermodynamic Properties of Phase Transitions 講授 11 Mixture Vapor-Liquid Equilibria 1. Mixture Vapor-Liquid Equilibrium in Ideal Mixtures 2. Vapor-Liquid Equilibrium in Nonideal Mixtures 1. Mixture Vapor-Liquid Equilibrium in Ideal Mixtures 2. Vapor-Liquid Equilibrium in Nonideal Mixtures 講授 作業 HW 6 5% 12 Thermodynamic Properties of Mixtues (I) 1. Partial Molar Gibbs Free Energy 2. Generalized Gibbs-Duhen Equation 3. Equation of Change for Multicoponent System 1. Partial Molar Gibbs Free Energy 2. Generalized Gibbs-Duhen Equation 3. Equation of Change for Multicoponent System 講授 13 Thermodynamic Properties of Mixtues (II) 1. Heat of Reaction 2. Criteria for Phase Equilibrium in Multicoponent Systems 3. Criteria for Chemical Equilibrium 4. Gisbbs Phase Rule 1. Heat of Reaction 2. Criteria for Phase Equilibrium in Multicoponent Systems 3. Criteria for Chemical Equilibrium 4. Gisbbs Phase Rule. 演講 14 Adsorption thermodynamics Single component adsorption isotherm To learn some single component adsorption isotherm models 講授 作業 HW 7 5% 15 Adsorption thermodynamics Multiple component adsorption isotherm To learn some multiple component adsorption isotherm models 講授 作業 HW 8 5% 16 Final exam Literature thermodynamic data analysis To present thermodynamic data analysis by poster and ppt 心得發表 期末考 Poster + PPT + Written report 30% 17 Project 1: Equation of State Data Analysis Project 1: Equation of State Data Analysis Project 1: Equation of State Data Analysis 實作 彈性教學 Project 1: Equation of State Data Analysis Report 5% 18 Project 2: Phase equilibrium Data Analysis Project 2: Phase equilibrium Data Analysis Project 2: Phase equilibrium Data Analysis 實作 彈性教學 Project 2: Phase equilibrium Data Analysis Report 5%

 序No. 實施期間Period 實施方式Content 教學說明Teaching instructions 彈性教學評量方式Evaluation 備註Notes 1 起:2024-06-10 迄:2024-06-15 5.小專題 Project Equation of State Data analysis Project 1 Equation of State Data analysis report 5% 2 起:2024-06-17 迄:2024-06-22 5.小專題 Project Phase equilibrium data analysis Project 2 Phase equilibrium data analysis report 5%

 教學要點概述： 1.自編教材 Handout by Instructor： □ 1-1.簡報 Slids □ 1-2.影音教材 Videos □ 1-3.教具 Teaching Aids □ 1-4.教科書 Textbook ■ 1-5.其他 Other □ 2.自編評量工具/量表 Educational Assessment □ 3.教科書作者提供 Textbook 成績考核 Performance Evaluation： 期末考：30%   期中考：20%   彈性教學：10%   作業：40%   教學資源(Teaching Resources)： □ 教材電子檔(Soft Copy of the Handout or the Textbook) □ 課程網站(Website) 課程網站(Website)：Wed Hard Disc 2, Sharing Name: 2019AdvThermo 扣考規定：https://curri.ttu.edu.tw/p/412-1033-1254.php